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3-Aminopyridinium trans-diaquadioxalatochromate(III)
In the structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], two crystallographically independent formula units are present. Both chromium atoms are six-coordinated in a distorted octahedral geometry by two chelating equatorial oxalato ligands and two axial water molecules. T...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393173/ https://www.ncbi.nlm.nih.gov/pubmed/22807741 http://dx.doi.org/10.1107/S1600536812025020 |
| _version_ | 1782237687914168320 |
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| author | Chérif, Ichraf Zid, Mohamed Faouzi El-Ghozzi, Malika Avignant, Daniel |
| author_facet | Chérif, Ichraf Zid, Mohamed Faouzi El-Ghozzi, Malika Avignant, Daniel |
| author_sort | Chérif, Ichraf |
| collection | PubMed |
| description | In the structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], two crystallographically independent formula units are present. Both chromium atoms are six-coordinated in a distorted octahedral geometry by two chelating equatorial oxalato ligands and two axial water molecules. The [Cr(C(2)O(4))(2)(H(2)O)(2)](−) anions and C(5)H(7)N(2) (+) cations are linked through a complex three-dimensional hydrogen-bonding network consisting of N—H⋯O and O—H⋯O interactions. |
| format | Online Article Text |
| id | pubmed-3393173 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931732012-07-17 3-Aminopyridinium trans-diaquadioxalatochromate(III) Chérif, Ichraf Zid, Mohamed Faouzi El-Ghozzi, Malika Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)], two crystallographically independent formula units are present. Both chromium atoms are six-coordinated in a distorted octahedral geometry by two chelating equatorial oxalato ligands and two axial water molecules. The [Cr(C(2)O(4))(2)(H(2)O)(2)](−) anions and C(5)H(7)N(2) (+) cations are linked through a complex three-dimensional hydrogen-bonding network consisting of N—H⋯O and O—H⋯O interactions. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393173/ /pubmed/22807741 http://dx.doi.org/10.1107/S1600536812025020 Text en © Chérif et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chérif, Ichraf Zid, Mohamed Faouzi El-Ghozzi, Malika Avignant, Daniel 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title | 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title_full | 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title_fullStr | 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title_full_unstemmed | 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title_short | 3-Aminopyridinium trans-diaquadioxalatochromate(III) |
| title_sort | 3-aminopyridinium trans-diaquadioxalatochromate(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393173/ https://www.ncbi.nlm.nih.gov/pubmed/22807741 http://dx.doi.org/10.1107/S1600536812025020 |
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