catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]

In the title coordination polymer, [Hg(2)Cl(4)(C(26)H(20)N(6))](n), one Hg(II) ion is coordinated by four N atoms from the benzylbis((pyridin-2-yl)methyl­idenehydrazone) ligand and two Cl(−) ions in a very distorted cis-HgCl(2)N(4) octa­hedral geometry. The other Hg(II) ion is coordinated in a disto...

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Autores principales: Akkurt, Mehmet, Khandar, Ali Akbar, Tahir, Muhammad Nawaz, Hosseini-Yazdi, Seyed Abolfazl, Mahmoudi, Ghodrat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393175/
https://www.ncbi.nlm.nih.gov/pubmed/22807743
http://dx.doi.org/10.1107/S1600536812025718
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author Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Hosseini-Yazdi, Seyed Abolfazl
Mahmoudi, Ghodrat
author_facet Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Hosseini-Yazdi, Seyed Abolfazl
Mahmoudi, Ghodrat
author_sort Akkurt, Mehmet
collection PubMed
description In the title coordination polymer, [Hg(2)Cl(4)(C(26)H(20)N(6))](n), one Hg(II) ion is coordinated by four N atoms from the benzylbis((pyridin-2-yl)methyl­idenehydrazone) ligand and two Cl(−) ions in a very distorted cis-HgCl(2)N(4) octa­hedral geometry. The other Hg(II) ion is coordinated in a distorted tetra­hedral geometry by four Cl(−) ions. Bridging chloride ions link the Hg(II) ions into a chain propagating in [010]: the Hg—Cl bridging bonds are significantly longer than the terminal bonds. The dihedral angle between the central benzene rings of the ligand is 83.3 (2)°. The packing is consolidated by weak C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-33931752012-07-17 catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido] Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Hosseini-Yazdi, Seyed Abolfazl Mahmoudi, Ghodrat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Hg(2)Cl(4)(C(26)H(20)N(6))](n), one Hg(II) ion is coordinated by four N atoms from the benzylbis((pyridin-2-yl)methyl­idenehydrazone) ligand and two Cl(−) ions in a very distorted cis-HgCl(2)N(4) octa­hedral geometry. The other Hg(II) ion is coordinated in a distorted tetra­hedral geometry by four Cl(−) ions. Bridging chloride ions link the Hg(II) ions into a chain propagating in [010]: the Hg—Cl bridging bonds are significantly longer than the terminal bonds. The dihedral angle between the central benzene rings of the ligand is 83.3 (2)°. The packing is consolidated by weak C—H⋯Cl hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393175/ /pubmed/22807743 http://dx.doi.org/10.1107/S1600536812025718 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Hosseini-Yazdi, Seyed Abolfazl
Mahmoudi, Ghodrat
catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title_full catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title_fullStr catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title_full_unstemmed catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title_short catena-Poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) N,N′,N′′,N′′′)mercury(II)]-μ-chlorido-[dichloridomercury(II)]-μ-chlorido]
title_sort catena-poly[[(benzil bis{[(pyridin-2-yl)methylidene]hydrazone}-κ(4) n,n′,n′′,n′′′)mercury(ii)]-μ-chlorido-[dichloridomercury(ii)]-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393175/
https://www.ncbi.nlm.nih.gov/pubmed/22807743
http://dx.doi.org/10.1107/S1600536812025718
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