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2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate
In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393176/ https://www.ncbi.nlm.nih.gov/pubmed/22807744 http://dx.doi.org/10.1107/S1600536812025111 |
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author | Bahojb Noruzi, Ehsan Safari, Nasser Amani, Vahid Notash, Behrouz |
author_facet | Bahojb Noruzi, Ehsan Safari, Nasser Amani, Vahid Notash, Behrouz |
author_sort | Bahojb Noruzi, Ehsan |
collection | PubMed |
description | In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetrahedral geometry. H atoms of the methanol molecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and intermolecular O—H⋯N and N—H⋯O hydrogen bonds stabilize the structure. |
format | Online Article Text |
id | pubmed-3393176 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931762012-07-17 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate Bahojb Noruzi, Ehsan Safari, Nasser Amani, Vahid Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent molecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetrahedral geometry. H atoms of the methanol molecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and intermolecular O—H⋯N and N—H⋯O hydrogen bonds stabilize the structure. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393176/ /pubmed/22807744 http://dx.doi.org/10.1107/S1600536812025111 Text en © Bahojb Noruzi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bahojb Noruzi, Ehsan Safari, Nasser Amani, Vahid Notash, Behrouz 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title | 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title_full | 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title_fullStr | 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title_full_unstemmed | 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title_short | 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(III) methanol monosolvate |
title_sort | 2,9-dimethyl-1,10-phenanthrolin-1-ium tetrachloridoferrate(iii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393176/ https://www.ncbi.nlm.nih.gov/pubmed/22807744 http://dx.doi.org/10.1107/S1600536812025111 |
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