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2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate

In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent mol­ecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a...

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Autores principales: Bahojb Noruzi, Ehsan, Safari, Nasser, Amani, Vahid, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393176/
https://www.ncbi.nlm.nih.gov/pubmed/22807744
http://dx.doi.org/10.1107/S1600536812025111
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author Bahojb Noruzi, Ehsan
Safari, Nasser
Amani, Vahid
Notash, Behrouz
author_facet Bahojb Noruzi, Ehsan
Safari, Nasser
Amani, Vahid
Notash, Behrouz
author_sort Bahojb Noruzi, Ehsan
collection PubMed
description In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent mol­ecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetra­hedral geometry. H atoms of the methanol mol­ecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and inter­molecular O—H⋯N and N—H⋯O hydrogen bonds stabilize the structure.
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spelling pubmed-33931762012-07-17 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate Bahojb Noruzi, Ehsan Safari, Nasser Amani, Vahid Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(13)N(2))[FeCl(4)]·CH(3)OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl(4) (−) anion and methanol solvent mol­ecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetra­hedral geometry. H atoms of the methanol mol­ecule are disordered over two sets of sites around the twofold axis. In the crystal, π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.6535 (16) and 3.5522 (17) Å] and inter­molecular O—H⋯N and N—H⋯O hydrogen bonds stabilize the structure. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393176/ /pubmed/22807744 http://dx.doi.org/10.1107/S1600536812025111 Text en © Bahojb Noruzi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bahojb Noruzi, Ehsan
Safari, Nasser
Amani, Vahid
Notash, Behrouz
2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title_full 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title_fullStr 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title_full_unstemmed 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title_short 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(III) methanol monosolvate
title_sort 2,9-dimethyl-1,10-phenanthrolin-1-ium tetra­chloridoferrate(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393176/
https://www.ncbi.nlm.nih.gov/pubmed/22807744
http://dx.doi.org/10.1107/S1600536812025111
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