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Di-μ-adipato-κ(4) O (1):O (6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occ...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393177/ https://www.ncbi.nlm.nih.gov/pubmed/22807745 http://dx.doi.org/10.1107/S1600536812025676 |
Sumario: | In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water molecule is located at the apical position. Of the two water H atoms, one participates in an intramolecular hydrogen bond whereas the second participates in an intermolecular hydrogen bond, which leads to the formation of a chain along [010]. |
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