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Di-μ-adipato-κ(4) O (1):O (6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occ...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393177/ https://www.ncbi.nlm.nih.gov/pubmed/22807745 http://dx.doi.org/10.1107/S1600536812025676 |
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author | Xu, Wei Qi, Jin–Li |
author_facet | Xu, Wei Qi, Jin–Li |
author_sort | Xu, Wei |
collection | PubMed |
description | In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water molecule is located at the apical position. Of the two water H atoms, one participates in an intramolecular hydrogen bond whereas the second participates in an intermolecular hydrogen bond, which leads to the formation of a chain along [010]. |
format | Online Article Text |
id | pubmed-3393177 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931772012-07-17 Di-μ-adipato-κ(4) O (1):O (6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} Xu, Wei Qi, Jin–Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water molecule is located at the apical position. Of the two water H atoms, one participates in an intramolecular hydrogen bond whereas the second participates in an intermolecular hydrogen bond, which leads to the formation of a chain along [010]. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393177/ /pubmed/22807745 http://dx.doi.org/10.1107/S1600536812025676 Text en © Xu and Qi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Wei Qi, Jin–Li Di-μ-adipato-κ(4) O (1):O (6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} |
title | Di-μ-adipato-κ(4)
O
(1):O
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_full | Di-μ-adipato-κ(4)
O
(1):O
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_fullStr | Di-μ-adipato-κ(4)
O
(1):O
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_full_unstemmed | Di-μ-adipato-κ(4)
O
(1):O
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_short | Di-μ-adipato-κ(4)
O
(1):O
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_sort | di-μ-adipato-κ(4)
o
(1):o
(6)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
n
(2),n
(3)]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393177/ https://www.ncbi.nlm.nih.gov/pubmed/22807745 http://dx.doi.org/10.1107/S1600536812025676 |
work_keys_str_mv | AT xuwei dimadipatok4o1o6bisaqua56diphenyl3pyridin2yl124triazinek2n2n3copperii AT qijinli dimadipatok4o1o6bisaqua56diphenyl3pyridin2yl124triazinek2n2n3copperii |