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Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}

In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyrid­yl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occ...

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Detalles Bibliográficos
Autores principales: Xu, Wei, Qi, Jin–Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393177/
https://www.ncbi.nlm.nih.gov/pubmed/22807745
http://dx.doi.org/10.1107/S1600536812025676
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author Xu, Wei
Qi, Jin–Li
author_facet Xu, Wei
Qi, Jin–Li
author_sort Xu, Wei
collection PubMed
description In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyrid­yl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water mol­ecule is located at the apical position. Of the two water H atoms, one participates in an intra­molecular hydrogen bond whereas the second participates in an inter­molecular hydrogen bond, which leads to the formation of a chain along [010].
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spelling pubmed-33931772012-07-17 Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} Xu, Wei Qi, Jin–Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Cu(2)(C(6)H(8)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)] or [Cu(2)(PDPT)(2)(C(6)H(8)O(4))(2)(H(2)O)(2)] (PDPT = 3-(2-pyrid­yl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water mol­ecule is located at the apical position. Of the two water H atoms, one participates in an intra­molecular hydrogen bond whereas the second participates in an inter­molecular hydrogen bond, which leads to the formation of a chain along [010]. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393177/ /pubmed/22807745 http://dx.doi.org/10.1107/S1600536812025676 Text en © Xu and Qi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Wei
Qi, Jin–Li
Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_full Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_fullStr Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_full_unstemmed Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_short Di-μ-adipato-κ(4) O (1):O (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_sort di-μ-adipato-κ(4) o (1):o (6)-bis­{aqua­[5,6-di­phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) n (2),n (3)]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393177/
https://www.ncbi.nlm.nih.gov/pubmed/22807745
http://dx.doi.org/10.1107/S1600536812025676
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AT qijinli dimadipatok4o1o6bisaqua56diphenyl3pyridin2yl124triazinek2n2n3copperii