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Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)vanadium(IV)
In the title V(IV) complex, [VO(C(13)H(15)NO(3))(C(12)H(8)N(2))], the oxidovanadium cation is N,N′-chelated by a 1-10-phenanthroline ligand and N,O,O′-chelated by a Schiff base anion in a distorted octahedral geometry. Weak intermolecular C—H⋯O hydrogen bonds occur in the crystal structure which c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393178/ https://www.ncbi.nlm.nih.gov/pubmed/22807746 http://dx.doi.org/10.1107/S1600536812025391 |
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author | Wang, Cheng-Yuan Jing, Bu-Qin Dong, Jian-Fang Li, Lian-Zhi |
author_facet | Wang, Cheng-Yuan Jing, Bu-Qin Dong, Jian-Fang Li, Lian-Zhi |
author_sort | Wang, Cheng-Yuan |
collection | PubMed |
description | In the title V(IV) complex, [VO(C(13)H(15)NO(3))(C(12)H(8)N(2))], the oxidovanadium cation is N,N′-chelated by a 1-10-phenanthroline ligand and N,O,O′-chelated by a Schiff base anion in a distorted octahedral geometry. Weak intermolecular C—H⋯O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81 Å(3). |
format | Online Article Text |
id | pubmed-3393178 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931782012-07-17 Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)vanadium(IV) Wang, Cheng-Yuan Jing, Bu-Qin Dong, Jian-Fang Li, Lian-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title V(IV) complex, [VO(C(13)H(15)NO(3))(C(12)H(8)N(2))], the oxidovanadium cation is N,N′-chelated by a 1-10-phenanthroline ligand and N,O,O′-chelated by a Schiff base anion in a distorted octahedral geometry. Weak intermolecular C—H⋯O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81 Å(3). International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393178/ /pubmed/22807746 http://dx.doi.org/10.1107/S1600536812025391 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Cheng-Yuan Jing, Bu-Qin Dong, Jian-Fang Li, Lian-Zhi Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)vanadium(IV) |
title | Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2)
N,O](1,10-phenanthroline-κ(2)
N,N′)vanadium(IV) |
title_full | Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2)
N,O](1,10-phenanthroline-κ(2)
N,N′)vanadium(IV) |
title_fullStr | Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2)
N,O](1,10-phenanthroline-κ(2)
N,N′)vanadium(IV) |
title_full_unstemmed | Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2)
N,O](1,10-phenanthroline-κ(2)
N,N′)vanadium(IV) |
title_short | Oxido[N-(2-oxidobenzylidene-κO)leucinato-κ(2)
N,O](1,10-phenanthroline-κ(2)
N,N′)vanadium(IV) |
title_sort | oxido[n-(2-oxidobenzylidene-κo)leucinato-κ(2)
n,o](1,10-phenanthroline-κ(2)
n,n′)vanadium(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393178/ https://www.ncbi.nlm.nih.gov/pubmed/22807746 http://dx.doi.org/10.1107/S1600536812025391 |
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