Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate

The asymmetric unit of the title complex, [Ni(C(10)H(8)N(2))(H(2)O)(4)]SO(4), consists of a complex [Ni(bipy)(H(2)O)(4)](2+) cation (bipy = 2,2′-bipyridine) and a non-coordinating [SO(4)](2−) anion. The Ni(II) atom is six-coordinated in a distorted octa­hedral geometry defined by the two N atoms of...

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Detalles Bibliográficos
Autores principales: Boonlue, Sujirat, Theppitak, Chatphorn, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393179/
https://www.ncbi.nlm.nih.gov/pubmed/22807747
http://dx.doi.org/10.1107/S160053681202538X
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author Boonlue, Sujirat
Theppitak, Chatphorn
Chainok, Kittipong
author_facet Boonlue, Sujirat
Theppitak, Chatphorn
Chainok, Kittipong
author_sort Boonlue, Sujirat
collection PubMed
description The asymmetric unit of the title complex, [Ni(C(10)H(8)N(2))(H(2)O)(4)]SO(4), consists of a complex [Ni(bipy)(H(2)O)(4)](2+) cation (bipy = 2,2′-bipyridine) and a non-coordinating [SO(4)](2−) anion. The Ni(II) atom is six-coordinated in a distorted octa­hedral geometry defined by the two N atoms of the bipy ligand and four water O atoms. The crystal structure contains extensive classical O—H⋯O hydrogen bonds, which link the ions into a two-dimensional array in the ab plane. Layers are connected into a three-dimensional supra­molecular structure by C—H⋯O inter­actions.
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spelling pubmed-33931792012-07-17 Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate Boonlue, Sujirat Theppitak, Chatphorn Chainok, Kittipong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Ni(C(10)H(8)N(2))(H(2)O)(4)]SO(4), consists of a complex [Ni(bipy)(H(2)O)(4)](2+) cation (bipy = 2,2′-bipyridine) and a non-coordinating [SO(4)](2−) anion. The Ni(II) atom is six-coordinated in a distorted octa­hedral geometry defined by the two N atoms of the bipy ligand and four water O atoms. The crystal structure contains extensive classical O—H⋯O hydrogen bonds, which link the ions into a two-dimensional array in the ab plane. Layers are connected into a three-dimensional supra­molecular structure by C—H⋯O inter­actions. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393179/ /pubmed/22807747 http://dx.doi.org/10.1107/S160053681202538X Text en © Boonlue et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boonlue, Sujirat
Theppitak, Chatphorn
Chainok, Kittipong
Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title_full Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title_fullStr Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title_full_unstemmed Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title_short Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II) sulfate
title_sort tetra­aqua­(2,2′-bipyridine-κ(2) n,n′)nickel(ii) sulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393179/
https://www.ncbi.nlm.nih.gov/pubmed/22807747
http://dx.doi.org/10.1107/S160053681202538X
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AT theppitakchatphorn tetraaqua22bipyridinek2nnnickeliisulfate
AT chainokkittipong tetraaqua22bipyridinek2nnnickeliisulfate

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