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n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)

Two independent mol­ecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each mol­ecule, the Sn(IV) atom exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, a...

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Detalles Bibliográficos
Autores principales: Affan, Md. Abu, Salam, Md. Abdus, Asaruddin, Mohd Razip, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393180/
https://www.ncbi.nlm.nih.gov/pubmed/22807748
http://dx.doi.org/10.1107/S1600536812025937
Descripción
Sumario:Two independent mol­ecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each mol­ecule, the Sn(IV) atom exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol­ecules are consolidated into a three-dimensional architecture by a combination of N—H⋯Cl, C—H⋯π and π–π inter­actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å].