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n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}tin(IV)
Two independent molecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each molecule, the Sn(IV) atom exists within a distorted octahedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393180/ https://www.ncbi.nlm.nih.gov/pubmed/22807748 http://dx.doi.org/10.1107/S1600536812025937 |
Sumario: | Two independent molecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each molecule, the Sn(IV) atom exists within a distorted octahedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, molecules are consolidated into a three-dimensional architecture by a combination of N—H⋯Cl, C—H⋯π and π–π interactions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å]. |
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