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n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)

Two independent mol­ecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each mol­ecule, the Sn(IV) atom exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, a...

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Autores principales: Affan, Md. Abu, Salam, Md. Abdus, Asaruddin, Mohd Razip, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393180/
https://www.ncbi.nlm.nih.gov/pubmed/22807748
http://dx.doi.org/10.1107/S1600536812025937
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author Affan, Md. Abu
Salam, Md. Abdus
Asaruddin, Mohd Razip
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Salam, Md. Abdus
Asaruddin, Mohd Razip
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each mol­ecule, the Sn(IV) atom exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol­ecules are consolidated into a three-dimensional architecture by a combination of N—H⋯Cl, C—H⋯π and π–π inter­actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å].
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spelling pubmed-33931802012-07-17 n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV) Affan, Md. Abu Salam, Md. Abdus Asaruddin, Mohd Razip Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent mol­ecules comprise the asymmetric unit in the title compound, [Sn(C(4)H(9))(C(14)H(19)N(4)S)Cl(2)]. In each mol­ecule, the Sn(IV) atom exists within a distorted octa­hedral geometry defined by the N,N′,S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol­ecules are consolidated into a three-dimensional architecture by a combination of N—H⋯Cl, C—H⋯π and π–π inter­actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å]. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393180/ /pubmed/22807748 http://dx.doi.org/10.1107/S1600536812025937 Text en © Affan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Salam, Md. Abdus
Asaruddin, Mohd Razip
Ng, Seik Weng
Tiekink, Edward R. T.
n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title_full n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title_fullStr n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title_full_unstemmed n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title_short n-Butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semi­carb­azi­dato-κ(2) N (1),S}tin(IV)
title_sort n-butyldichlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κn)ethyl­idene]thio­semi­carb­azi­dato-κ(2) n (1),s}tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393180/
https://www.ncbi.nlm.nih.gov/pubmed/22807748
http://dx.doi.org/10.1107/S1600536812025937
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