[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)

The Ni(II) atom in the title complex, [Ni(C(11)H(13)N(3)OS)(C(5)H(5)N)], exists within a square-planar N(3)O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite ang...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393181/
https://www.ncbi.nlm.nih.gov/pubmed/22807749
http://dx.doi.org/10.1107/S1600536812026177
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author Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Takjoo, Reza
collection PubMed
description The Ni(II) atom in the title complex, [Ni(C(11)H(13)N(3)OS)(C(5)H(5)N)], exists within a square-planar N(3)O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite angle of 83.28 (12)°. The pyridine mol­ecule forms a dihedral angle of 44.43 (6)° with the N(3)O donor set. Supra­molecular stacks along the a axis mediated by alternating π–π inter­actions between the pyridine and five- [centroid–centroid distance = 3.4784 (16) Å] and six-membered [3.4633 (17) Å] chelate rings, feature in the crystal packing.
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spelling pubmed-33931812012-07-17 [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II) Takjoo, Reza Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title complex, [Ni(C(11)H(13)N(3)OS)(C(5)H(5)N)], exists within a square-planar N(3)O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite angle of 83.28 (12)°. The pyridine mol­ecule forms a dihedral angle of 44.43 (6)° with the N(3)O donor set. Supra­molecular stacks along the a axis mediated by alternating π–π inter­actions between the pyridine and five- [centroid–centroid distance = 3.4784 (16) Å] and six-membered [3.4633 (17) Å] chelate rings, feature in the crystal packing. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393181/ /pubmed/22807749 http://dx.doi.org/10.1107/S1600536812026177 Text en © Takjoo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title_full [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title_fullStr [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title_full_unstemmed [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title_short [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](pyridine-κN)nickel(II)
title_sort [2-(1-{2-[aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κn]hydrazin-1-yl­idene-κn (1)}eth­yl)phenolato-κo](pyridine-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393181/
https://www.ncbi.nlm.nih.gov/pubmed/22807749
http://dx.doi.org/10.1107/S1600536812026177
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AT tiekinkedwardrt 212azanidylethylsulfanylmethylideneknhydrazin1ylidenekn1ethylphenolatokopyridineknnickelii

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