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catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate]
The title compound, [Mn(C(11)H(8)O(5))(C(12)H(8)N(2))(H(2)O)(2)]·H(2)O, was obtained under hydrothermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN(2)O(4) octahedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxylate O atoms f...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393182/ https://www.ncbi.nlm.nih.gov/pubmed/22807750 http://dx.doi.org/10.1107/S1600536812023896 |
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author | Ji, Jun Yang, Yuan-Fa Wen, Yi-Hang |
author_facet | Ji, Jun Yang, Yuan-Fa Wen, Yi-Hang |
author_sort | Ji, Jun |
collection | PubMed |
description | The title compound, [Mn(C(11)H(8)O(5))(C(12)H(8)N(2))(H(2)O)(2)]·H(2)O, was obtained under hydrothermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN(2)O(4) octahedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxylate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Intermolecular O—H⋯O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water molecules are present. |
format | Online Article Text |
id | pubmed-3393182 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931822012-07-17 catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] Ji, Jun Yang, Yuan-Fa Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(11)H(8)O(5))(C(12)H(8)N(2))(H(2)O)(2)]·H(2)O, was obtained under hydrothermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN(2)O(4) octahedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxylate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Intermolecular O—H⋯O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water molecules are present. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393182/ /pubmed/22807750 http://dx.doi.org/10.1107/S1600536812023896 Text en © Ji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ji, Jun Yang, Yuan-Fa Wen, Yi-Hang catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title |
catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title_full |
catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title_fullStr |
catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title_short |
catena-Poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
title_sort | catena-poly[[[diaqua(1,10-phenanthroline)manganese]-μ-3-[3-(carboxylatomethoxy)phenyl]acrylato] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393182/ https://www.ncbi.nlm.nih.gov/pubmed/22807750 http://dx.doi.org/10.1107/S1600536812023896 |
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