Cargando…
Bis[N,N-bis(diphenylphosphanyl)cyclopentanamine-κ(2) P,P′]platinum(II) bis(trifluoromethanesulfonate)
The title compound, [Pt(C(29)H(29)NP(2))(2)](CF(3)SO(3))(2), consists of a Pt(II) atom, situated on an inversion centre, coordinated by two diphosphinoamine bidentate ligands and charge-balanced by two trifluoromethanesulfonate anions. The Pt(II) atom has a distorted square-planar geometry defined...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393184/ https://www.ncbi.nlm.nih.gov/pubmed/22807752 http://dx.doi.org/10.1107/S1600536812026359 |
Sumario: | The title compound, [Pt(C(29)H(29)NP(2))(2)](CF(3)SO(3))(2), consists of a Pt(II) atom, situated on an inversion centre, coordinated by two diphosphinoamine bidentate ligands and charge-balanced by two trifluoromethanesulfonate anions. The Pt(II) atom has a distorted square-planar geometry defined by the four P atoms. The distortion is illustrated by the P—Pt—P bite angle of 70.31 (4)°. The geometry around the N atom deviates from a trigonal–planar geometry, evidenced by the P—N—P bite angle of 102.3 (2) °. The N atom is displaced by 0.114 (4) Å from the C/P/P plane. In order to coordinate, the orientation of the phenyl rings alters from a C(s) conformation to a C (2v) conformation. The cyclopentane ring is slightly twisted: the puckering parameters are q (2) = 0.420 (5) Å and ϕ = 26.5 (8) °. The trifluoromethanesulfonate anion displays a 0.511 (11):0.489 (11) positional disorder. Weak inter- and intramolecular C—H⋯O hydrogen bonds influence the crystal packing. |
---|