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Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2) N,N′}urea-κO)nickel(II) dinitrate
The Ni(II) atom in the title salt, [Ni(C(19)H(16)N(4)O)(2)](NO(3))(2), is N,N′,O-chelated by two neutral Schiff base ligands in a distorted octahedral geometry. One nitrate ion interacts with the metal atom indirectly, in an outer-sphere type of coordination, through N—H⋯O hydrogen bonds; the othe...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393185/ https://www.ncbi.nlm.nih.gov/pubmed/22807753 http://dx.doi.org/10.1107/S1600536812026207 |
| _version_ | 1782237690693943296 |
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| author | Aiswarya, N. Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng |
| author_facet | Aiswarya, N. Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng |
| author_sort | Aiswarya, N. |
| collection | PubMed |
| description | The Ni(II) atom in the title salt, [Ni(C(19)H(16)N(4)O)(2)](NO(3))(2), is N,N′,O-chelated by two neutral Schiff base ligands in a distorted octahedral geometry. One nitrate ion interacts with the metal atom indirectly, in an outer-sphere type of coordination, through N—H⋯O hydrogen bonds; the other nitrate ion does not engage in any interactions and is equally disordered over two positions in the crystal. |
| format | Online Article Text |
| id | pubmed-3393185 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931852012-07-17 Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2) N,N′}urea-κO)nickel(II) dinitrate Aiswarya, N. Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title salt, [Ni(C(19)H(16)N(4)O)(2)](NO(3))(2), is N,N′,O-chelated by two neutral Schiff base ligands in a distorted octahedral geometry. One nitrate ion interacts with the metal atom indirectly, in an outer-sphere type of coordination, through N—H⋯O hydrogen bonds; the other nitrate ion does not engage in any interactions and is equally disordered over two positions in the crystal. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393185/ /pubmed/22807753 http://dx.doi.org/10.1107/S1600536812026207 Text en © Aiswarya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Aiswarya, N. Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2) N,N′}urea-κO)nickel(II) dinitrate |
| title | Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
N,N′}urea-κO)nickel(II) dinitrate |
| title_full | Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
N,N′}urea-κO)nickel(II) dinitrate |
| title_fullStr | Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
N,N′}urea-κO)nickel(II) dinitrate |
| title_full_unstemmed | Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
N,N′}urea-κO)nickel(II) dinitrate |
| title_short | Bis(1-phenyl-3-{(Z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
N,N′}urea-κO)nickel(II) dinitrate |
| title_sort | bis(1-phenyl-3-{(z)-[phenyl(pyridin-2-yl)methylidene]amino-κ(2)
n,n′}urea-κo)nickel(ii) dinitrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393185/ https://www.ncbi.nlm.nih.gov/pubmed/22807753 http://dx.doi.org/10.1107/S1600536812026207 |
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