1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene

In the crystal structure of the title substituted ferrocene complex, [Fe(C(19)H(18)O(2)P)(2)], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo­penta­dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe—C bond-length range of 2.0239 (15)–2.0521 (15) Å...

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Detalles Bibliográficos
Autores principales: Ren, Xinfeng, Wang, Le, Li, Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393188/
https://www.ncbi.nlm.nih.gov/pubmed/22807756
http://dx.doi.org/10.1107/S1600536812026293
Descripción
Sumario:In the crystal structure of the title substituted ferrocene complex, [Fe(C(19)H(18)O(2)P)(2)], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo­penta­dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe—C bond-length range of 2.0239 (15)–2.0521 (15) Å. In the ligand, the cyclo­penta­dienyl ring forms dihedral angles of 60.36 (6) and 82.93 (6)° with the two benzene rings of the diphenyl­phosphine group, while the dihedral angle between the benzene rings is 67.4 (5)°.

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