1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene

In the crystal structure of the title substituted ferrocene complex, [Fe(C(19)H(18)O(2)P)(2)], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo­penta­dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe—C bond-length range of 2.0239 (15)–2.0521 (15) Å...

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Detalles Bibliográficos
Autores principales: Ren, Xinfeng, Wang, Le, Li, Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393188/
https://www.ncbi.nlm.nih.gov/pubmed/22807756
http://dx.doi.org/10.1107/S1600536812026293
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author Ren, Xinfeng
Wang, Le
Li, Ya
author_facet Ren, Xinfeng
Wang, Le
Li, Ya
author_sort Ren, Xinfeng
collection PubMed
description In the crystal structure of the title substituted ferrocene complex, [Fe(C(19)H(18)O(2)P)(2)], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo­penta­dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe—C bond-length range of 2.0239 (15)–2.0521 (15) Å. In the ligand, the cyclo­penta­dienyl ring forms dihedral angles of 60.36 (6) and 82.93 (6)° with the two benzene rings of the diphenyl­phosphine group, while the dihedral angle between the benzene rings is 67.4 (5)°.
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spelling pubmed-33931882012-07-17 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene Ren, Xinfeng Wang, Le Li, Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title substituted ferrocene complex, [Fe(C(19)H(18)O(2)P)(2)], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo­penta­dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe—C bond-length range of 2.0239 (15)–2.0521 (15) Å. In the ligand, the cyclo­penta­dienyl ring forms dihedral angles of 60.36 (6) and 82.93 (6)° with the two benzene rings of the diphenyl­phosphine group, while the dihedral angle between the benzene rings is 67.4 (5)°. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393188/ /pubmed/22807756 http://dx.doi.org/10.1107/S1600536812026293 Text en © Ren et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ren, Xinfeng
Wang, Le
Li, Ya
1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title_full 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title_fullStr 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title_full_unstemmed 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title_short 1,1′-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
title_sort 1,1′-bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393188/
https://www.ncbi.nlm.nih.gov/pubmed/22807756
http://dx.doi.org/10.1107/S1600536812026293
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AT liya 11bisbis4methoxyphenylphosphanylferrocene

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