[1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)

In the title complex, [Mn(C(6)H(2)N(3)O(7))(2)(C(30)H(26)N(4)O)], the Mn(II) atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with...

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Detalles Bibliográficos
Autores principales: Li, Congfen, Kou, Fan, Li, Xinghan, Wu, Hao, Wu, Huilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393189/
https://www.ncbi.nlm.nih.gov/pubmed/22807757
http://dx.doi.org/10.1107/S1600536812026037
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author Li, Congfen
Kou, Fan
Li, Xinghan
Wu, Hao
Wu, Huilu
author_facet Li, Congfen
Kou, Fan
Li, Xinghan
Wu, Hao
Wu, Huilu
author_sort Li, Congfen
collection PubMed
description In the title complex, [Mn(C(6)H(2)N(3)O(7))(2)(C(30)H(26)N(4)O)], the Mn(II) atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5).
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spelling pubmed-33931892012-07-17 [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II) Li, Congfen Kou, Fan Li, Xinghan Wu, Hao Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(6)H(2)N(3)O(7))(2)(C(30)H(26)N(4)O)], the Mn(II) atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5). International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393189/ /pubmed/22807757 http://dx.doi.org/10.1107/S1600536812026037 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Congfen
Kou, Fan
Li, Xinghan
Wu, Hao
Wu, Huilu
[1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title_full [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title_fullStr [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title_full_unstemmed [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title_short [1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ(3) N (3),O,N (3′)]bis(2,4,6-trinitrophenolato-κO (1))manganese(II)
title_sort [1,1′-dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1h-benzimidazole)-κ(3) n (3),o,n (3′)]bis(2,4,6-trinitrophenolato-κo (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393189/
https://www.ncbi.nlm.nih.gov/pubmed/22807757
http://dx.doi.org/10.1107/S1600536812026037
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