Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)

In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra­hedral coordination geometry best described as bis­phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro­gen...

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Detalles Bibliográficos
Autores principales: Islam, M. A. A. A. A., Reza, M. S., Tarafder, M. T. H., Sheikh, M. C., Zangrando, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393190/
https://www.ncbi.nlm.nih.gov/pubmed/22807758
http://dx.doi.org/10.1107/S1600536812025901
Descripción
Sumario:In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra­hedral coordination geometry best described as bis­phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro­gen and the thiol­ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C—H⋯S inter­actions give rise to chains extending along the c axis.

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