Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)

In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra­hedral coordination geometry best described as bis­phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro­gen...

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Detalles Bibliográficos
Autores principales: Islam, M. A. A. A. A., Reza, M. S., Tarafder, M. T. H., Sheikh, M. C., Zangrando, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393190/
https://www.ncbi.nlm.nih.gov/pubmed/22807758
http://dx.doi.org/10.1107/S1600536812025901
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author Islam, M. A. A. A. A.
Reza, M. S.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
author_facet Islam, M. A. A. A. A.
Reza, M. S.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
author_sort Islam, M. A. A. A. A.
collection PubMed
description In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra­hedral coordination geometry best described as bis­phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro­gen and the thiol­ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C—H⋯S inter­actions give rise to chains extending along the c axis.
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spelling pubmed-33931902012-07-17 Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II) Islam, M. A. A. A. A. Reza, M. S. Tarafder, M. T. H. Sheikh, M. C. Zangrando, E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra­hedral coordination geometry best described as bis­phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro­gen and the thiol­ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C—H⋯S inter­actions give rise to chains extending along the c axis. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393190/ /pubmed/22807758 http://dx.doi.org/10.1107/S1600536812025901 Text en © Islam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Islam, M. A. A. A. A.
Reza, M. S.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title_full Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title_fullStr Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title_full_unstemmed Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title_short Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N′,S]mercury(II)
title_sort bis[benzyl n′-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) n′,s]mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393190/
https://www.ncbi.nlm.nih.gov/pubmed/22807758
http://dx.doi.org/10.1107/S1600536812025901
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