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catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2) O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2) O:O′]] monohydrate]
In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxylate group, four monodentate bridging carboxylate O atoms and two water molecules. The resulting GdO(8) polyhedron approximates to a square antiprism. The bridging...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393192/ https://www.ncbi.nlm.nih.gov/pubmed/22807760 http://dx.doi.org/10.1107/S1600536812026153 |
| _version_ | 1782237692336013312 |
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| author | Li, Dong-Ying Li, Guo-Ting |
| author_facet | Li, Dong-Ying Li, Guo-Ting |
| author_sort | Li, Dong-Ying |
| collection | PubMed |
| description | In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxylate group, four monodentate bridging carboxylate O atoms and two water molecules. The resulting GdO(8) polyhedron approximates to a square antiprism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O—H⋯O and O—H⋯N hydrogen bonds help to establish the packing. |
| format | Online Article Text |
| id | pubmed-3393192 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931922012-07-17 catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2) O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2) O:O′]] monohydrate] Li, Dong-Ying Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxylate group, four monodentate bridging carboxylate O atoms and two water molecules. The resulting GdO(8) polyhedron approximates to a square antiprism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O—H⋯O and O—H⋯N hydrogen bonds help to establish the packing. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393192/ /pubmed/22807760 http://dx.doi.org/10.1107/S1600536812026153 Text en © Li and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Dong-Ying Li, Guo-Ting catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2) O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2) O:O′]] monohydrate] |
| title |
catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
O:O′]] monohydrate] |
| title_full |
catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
O:O′]] monohydrate] |
| title_fullStr |
catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
O:O′]] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
O:O′]] monohydrate] |
| title_short |
catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
O,O′]gadolinium(III)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
O:O′]] monohydrate] |
| title_sort | catena-poly[[[diaqua[3-(pyridin-4-yl)benzoato-κ(2)
o,o′]gadolinium(iii)]-bis[μ-3-(pyridin-4-yl)benzoato-κ(2)
o:o′]] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393192/ https://www.ncbi.nlm.nih.gov/pubmed/22807760 http://dx.doi.org/10.1107/S1600536812026153 |
| work_keys_str_mv | AT lidongying catenapolydiaqua3pyridin4ylbenzoatok2oogadoliniumiiibism3pyridin4ylbenzoatok2oomonohydrate AT liguoting catenapolydiaqua3pyridin4ylbenzoatok2oogadoliniumiiibism3pyridin4ylbenzoatok2oomonohydrate |