Cargando…

[N,N′-Bis(2,4,6-trimethyl­phen­yl)ethane-1,2-diimine-κ(2) N,N′]tetra­carbonyl­chromium(0)

The octa­hedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbon­yl) that deviates by more than 20° from planarity. Another structural feature is the significant d...

Descripción completa

Detalles Bibliográficos
Autores principales: Landman, Marilé, Fraser, Roan, Pretorius, René, Prinsloo, Rohen, Liles, David C., van Rooyen, Petrus H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393193/
https://www.ncbi.nlm.nih.gov/pubmed/22807761
http://dx.doi.org/10.1107/S1600536812024786
Descripción
Sumario:The octa­hedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbon­yl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that inter­act with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°.