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[N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2) N,N′]tetracarbonylchromium(0)
The octahedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant d...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393193/ https://www.ncbi.nlm.nih.gov/pubmed/22807761 http://dx.doi.org/10.1107/S1600536812024786 |
Sumario: | The octahedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that interact with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°. |
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