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[N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2) N,N′]tetracarbonylchromium(0)
The octahedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant d...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393193/ https://www.ncbi.nlm.nih.gov/pubmed/22807761 http://dx.doi.org/10.1107/S1600536812024786 |
| _version_ | 1782237692568797184 |
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| author | Landman, Marilé Fraser, Roan Pretorius, René Prinsloo, Rohen Liles, David C. van Rooyen, Petrus H. |
| author_facet | Landman, Marilé Fraser, Roan Pretorius, René Prinsloo, Rohen Liles, David C. van Rooyen, Petrus H. |
| author_sort | Landman, Marilé |
| collection | PubMed |
| description | The octahedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that interact with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°. |
| format | Online Article Text |
| id | pubmed-3393193 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931932012-07-17 [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2) N,N′]tetracarbonylchromium(0) Landman, Marilé Fraser, Roan Pretorius, René Prinsloo, Rohen Liles, David C. van Rooyen, Petrus H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The octahedral coordination of the Cr(0) atom in the title compound, [Cr(C(20)H(24)N(2))(CO)(4)], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that interact with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393193/ /pubmed/22807761 http://dx.doi.org/10.1107/S1600536812024786 Text en © Landman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Landman, Marilé Fraser, Roan Pretorius, René Prinsloo, Rohen Liles, David C. van Rooyen, Petrus H. [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2) N,N′]tetracarbonylchromium(0) |
| title | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
N,N′]tetracarbonylchromium(0) |
| title_full | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
N,N′]tetracarbonylchromium(0) |
| title_fullStr | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
N,N′]tetracarbonylchromium(0) |
| title_full_unstemmed | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
N,N′]tetracarbonylchromium(0) |
| title_short | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
N,N′]tetracarbonylchromium(0) |
| title_sort | [n,n′-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ(2)
n,n′]tetracarbonylchromium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393193/ https://www.ncbi.nlm.nih.gov/pubmed/22807761 http://dx.doi.org/10.1107/S1600536812024786 |
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