Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate

In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta­methyl­cyclo­penta­dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa­methyl­ene­tetra­m...

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Detalles Bibliográficos
Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393194/
https://www.ncbi.nlm.nih.gov/pubmed/22807762
http://dx.doi.org/10.1107/S1600536812026360
Descripción
Sumario:In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta­methyl­cyclo­penta­dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa­methyl­ene­tetra­mine ligand occupy the remaining coordination sites, completing a pseudo-octahedral geometry. Both the complex cation and the BF(4) (−) anion reside on crystallographic mirror planes. The Fe—N bond length is 2.069 (2) and the Fe—Cp*(centroid) distance is 1.7452 (3) Å.

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