Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate

In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta­methyl­cyclo­penta­dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa­methyl­ene­tetra­m...

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Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393194/
https://www.ncbi.nlm.nih.gov/pubmed/22807762
http://dx.doi.org/10.1107/S1600536812026360
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author M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
author_facet M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
author_sort M’thiruaine, Cyprian M.
collection PubMed
description In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta­methyl­cyclo­penta­dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa­methyl­ene­tetra­mine ligand occupy the remaining coordination sites, completing a pseudo-octahedral geometry. Both the complex cation and the BF(4) (−) anion reside on crystallographic mirror planes. The Fe—N bond length is 2.069 (2) and the Fe—Cp*(centroid) distance is 1.7452 (3) Å.
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spelling pubmed-33931942012-07-17 Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Fernandes, Manuel A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta­methyl­cyclo­penta­dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa­methyl­ene­tetra­mine ligand occupy the remaining coordination sites, completing a pseudo-octahedral geometry. Both the complex cation and the BF(4) (−) anion reside on crystallographic mirror planes. The Fe—N bond length is 2.069 (2) and the Fe—Cp*(centroid) distance is 1.7452 (3) Å. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393194/ /pubmed/22807762 http://dx.doi.org/10.1107/S1600536812026360 Text en © M'thiruaine et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_full Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_fullStr Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_full_unstemmed Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_short Dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κN (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_sort dicarbon­yl(hexa­methyl­ene-1,3,5,7-tetra­mine-κn (1))(η(5)-penta­methyl­cyclo­penta­dien­yl)iron(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393194/
https://www.ncbi.nlm.nih.gov/pubmed/22807762
http://dx.doi.org/10.1107/S1600536812026360
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