Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate

The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe—N bond length is 2.011 (3) Å and the Fe—Cp centroid distance is 1.7189 (5) Å. In...

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Detalles Bibliográficos
Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393195/
https://www.ncbi.nlm.nih.gov/pubmed/22807763
http://dx.doi.org/10.1107/S1600536812025925
Descripción
Sumario:The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe—N bond length is 2.011 (3) Å and the Fe—Cp centroid distance is 1.7189 (5) Å. In the crystal, the ions are linked via two N—H⋯F inter­actions and a weak N—H⋯Br inter­action.

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