Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate

The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe—N bond length is 2.011 (3) Å and the Fe—Cp centroid distance is 1.7189 (5) Å. In...

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Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393195/
https://www.ncbi.nlm.nih.gov/pubmed/22807763
http://dx.doi.org/10.1107/S1600536812025925
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author M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
author_facet M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
author_sort M’thiruaine, Cyprian M.
collection PubMed
description The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe—N bond length is 2.011 (3) Å and the Fe—Cp centroid distance is 1.7189 (5) Å. In the crystal, the ions are linked via two N—H⋯F inter­actions and a weak N—H⋯Br inter­action.
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spelling pubmed-33931952012-07-17 Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Fernandes, Manuel A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe—N bond length is 2.011 (3) Å and the Fe—Cp centroid distance is 1.7189 (5) Å. In the crystal, the ions are linked via two N—H⋯F inter­actions and a weak N—H⋯Br inter­action. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393195/ /pubmed/22807763 http://dx.doi.org/10.1107/S1600536812025925 Text en © M'thiruaine et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
M’thiruaine, Cyprian M.
Friedrich, Holger B.
Changamu, Evans O.
Fernandes, Manuel A.
Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title_full Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title_fullStr Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title_full_unstemmed Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title_short Dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κN)iron(II) tetra­fluoridoborate
title_sort dicarbon­yl(η(5)-cyclo­penta­dien­yl)(2,3-di­bromo­propanamine-κn)iron(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393195/
https://www.ncbi.nlm.nih.gov/pubmed/22807763
http://dx.doi.org/10.1107/S1600536812025925
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