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Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]

The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxyl­ate ligands with a bridging carboxyl­ate group, and two aqua O atoms also in a bridging mode....

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393196/
https://www.ncbi.nlm.nih.gov/pubmed/22807764
http://dx.doi.org/10.1107/S1600536812024683
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxyl­ate ligands with a bridging carboxyl­ate group, and two aqua O atoms also in a bridging mode. The symmetry-related Li(I) ions bridged by a carboxyl­ate O atom and a coordinating water O atom form an Li(2)O(2) unit with an Li⋯Li distance of 3.052 (4) Å, which generates mol­ecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H⋯O hydrogen bonds in which the coordinating water mol­ecules act as donors and the carboxyl­ate O atoms as acceptors.
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spelling pubmed-33931962012-07-17 Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxyl­ate ligands with a bridging carboxyl­ate group, and two aqua O atoms also in a bridging mode. The symmetry-related Li(I) ions bridged by a carboxyl­ate O atom and a coordinating water O atom form an Li(2)O(2) unit with an Li⋯Li distance of 3.052 (4) Å, which generates mol­ecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H⋯O hydrogen bonds in which the coordinating water mol­ecules act as donors and the carboxyl­ate O atoms as acceptors. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393196/ /pubmed/22807764 http://dx.doi.org/10.1107/S1600536812024683 Text en © Starosta and Leciejewicz 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title_full Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title_fullStr Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title_full_unstemmed Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title_short Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
title_sort poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxyl­ato)-lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393196/
https://www.ncbi.nlm.nih.gov/pubmed/22807764
http://dx.doi.org/10.1107/S1600536812024683
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