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Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium]
The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393196/ https://www.ncbi.nlm.nih.gov/pubmed/22807764 http://dx.doi.org/10.1107/S1600536812024683 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related Li(I) ions bridged by a carboxylate O atom and a coordinating water O atom form an Li(2)O(2) unit with an Li⋯Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H⋯O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors. |
format | Online Article Text |
id | pubmed-3393196 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931962012-07-17 Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), contains an Li(I) ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related Li(I) ions bridged by a carboxylate O atom and a coordinating water O atom form an Li(2)O(2) unit with an Li⋯Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H⋯O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393196/ /pubmed/22807764 http://dx.doi.org/10.1107/S1600536812024683 Text en © Starosta and Leciejewicz 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title | Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title_full | Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title_fullStr | Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title_full_unstemmed | Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title_short | Poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
title_sort | poly[μ(2)-aqua-μ(2)-(pyrazine-2-carboxylato)-lithium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393196/ https://www.ncbi.nlm.nih.gov/pubmed/22807764 http://dx.doi.org/10.1107/S1600536812024683 |
work_keys_str_mv | AT starostawojciech polym2aquam2pyrazine2carboxylatolithium AT leciejewiczjanusz polym2aquam2pyrazine2carboxylatolithium |