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{4,4′,6,6′-Tetraiodo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II)
The asymmetric unit of the title compound, [Ni(C(19)H(16)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the Ni(II) atom is disto...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393197/ https://www.ncbi.nlm.nih.gov/pubmed/22807765 http://dx.doi.org/10.1107/S1600536812024944 |
Sumario: | The asymmetric unit of the title compound, [Ni(C(19)H(16)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the Ni(II) atom is distorted square-planar, with a dihedral angle of 21.7 (3)° between the symmetry-related N/Ni/O coordination planes. The dihedral angle between the symmetry-related benzene rings is 27.9 (3)°. In the crystal, short intermolecular I⋯I [3.8178 (9) and 3.9013 (10) Å] interactions are present. |
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