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Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc
The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent molecules. The geometry around the Zn(II) atoms is distorted trigonal–bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393198/ https://www.ncbi.nlm.nih.gov/pubmed/22807766 http://dx.doi.org/10.1107/S1600536812025986 |
Sumario: | The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent molecules. The geometry around the Zn(II) atoms is distorted trigonal–bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating water molecule. The dihedral angles between the benzene rings in the two molecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent molecules are linked by pairs of O—H⋯O hydrogen bonds, forming dimers with R (2) (2)(6) ring motifs, and by O—H⋯Cl hydrogen bonds. There are short Cl⋯Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and molecules are also linked by C—H⋯O and π–π [centroid–centroid distance = 3.671 (2) Å] interactions. |
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