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Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc
The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent molecules. The geometry around the Zn(II) atoms is distorted trigonal–bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393198/ https://www.ncbi.nlm.nih.gov/pubmed/22807766 http://dx.doi.org/10.1107/S1600536812025986 |
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author | Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent molecules. The geometry around the Zn(II) atoms is distorted trigonal–bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating water molecule. The dihedral angles between the benzene rings in the two molecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent molecules are linked by pairs of O—H⋯O hydrogen bonds, forming dimers with R (2) (2)(6) ring motifs, and by O—H⋯Cl hydrogen bonds. There are short Cl⋯Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and molecules are also linked by C—H⋯O and π–π [centroid–centroid distance = 3.671 (2) Å] interactions. |
format | Online Article Text |
id | pubmed-3393198 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931982012-07-17 Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent molecules. The geometry around the Zn(II) atoms is distorted trigonal–bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating water molecule. The dihedral angles between the benzene rings in the two molecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent molecules are linked by pairs of O—H⋯O hydrogen bonds, forming dimers with R (2) (2)(6) ring motifs, and by O—H⋯Cl hydrogen bonds. There are short Cl⋯Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and molecules are also linked by C—H⋯O and π–π [centroid–centroid distance = 3.671 (2) Å] interactions. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393198/ /pubmed/22807766 http://dx.doi.org/10.1107/S1600536812025986 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title | Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title_full | Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title_fullStr | Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title_full_unstemmed | Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title_short | Aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
title_sort | aqua{4,4′,6,6′-tetrachloro-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393198/ https://www.ncbi.nlm.nih.gov/pubmed/22807766 http://dx.doi.org/10.1107/S1600536812025986 |
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