Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]

The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol­ecule, the structural dimeric unit being generated by inversio...

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Detalles Bibliográficos
Autores principales: Nesbit, Mark A., Gray, Danielle L., Girolami, Gregory S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393201/
https://www.ncbi.nlm.nih.gov/pubmed/22807769
http://dx.doi.org/10.1107/S1600536812025445
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author Nesbit, Mark A.
Gray, Danielle L.
Girolami, Gregory S.
author_facet Nesbit, Mark A.
Gray, Danielle L.
Girolami, Gregory S.
author_sort Nesbit, Mark A.
collection PubMed
description The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol­ecule, the structural dimeric unit being generated by inversion symmetry with an Mg⋯Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals inter­actions only.
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spelling pubmed-33932012012-07-17 Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium] Nesbit, Mark A. Gray, Danielle L. Girolami, Gregory S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol­ecule, the structural dimeric unit being generated by inversion symmetry with an Mg⋯Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals inter­actions only. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393201/ /pubmed/22807769 http://dx.doi.org/10.1107/S1600536812025445 Text en © Nesbit et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nesbit, Mark A.
Gray, Danielle L.
Girolami, Gregory S.
Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title_full Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title_fullStr Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title_full_unstemmed Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title_short Di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
title_sort di-μ-bromido-bis­[benz­yl(diethyl ether)magnesium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393201/
https://www.ncbi.nlm.nih.gov/pubmed/22807769
http://dx.doi.org/10.1107/S1600536812025445
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