[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)

The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa­hedral N(2)O(4) donor set. The most prominent feature of the crystal packi...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393203/
https://www.ncbi.nlm.nih.gov/pubmed/22807771
http://dx.doi.org/10.1107/S1600536812026566
Descripción
Sumario:The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa­hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N—H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.

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