[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)

The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa­hedral N(2)O(4) donor set. The most prominent feature of the crystal packi...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393203/
https://www.ncbi.nlm.nih.gov/pubmed/22807771
http://dx.doi.org/10.1107/S1600536812026566
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author Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Takjoo, Reza
collection PubMed
description The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa­hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N—H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.
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spelling pubmed-33932032012-07-17 [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI) Takjoo, Reza Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N′,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa­hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N—H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393203/ /pubmed/22807771 http://dx.doi.org/10.1107/S1600536812026566 Text en © Takjoo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takjoo, Reza
Ng, Seik Weng
Tiekink, Edward R. T.
[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title_full [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title_fullStr [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title_full_unstemmed [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title_short [2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN (1)}eth­yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI)
title_sort [2-(1-{2-[aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κn]hydrazin-1-yl­idene-κn (1)}eth­yl)phenolato-κo](dimethyl sulfoxide-κo)dioxidomolybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393203/
https://www.ncbi.nlm.nih.gov/pubmed/22807771
http://dx.doi.org/10.1107/S1600536812026566
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