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Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)

In the title complex, [Ni(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) cat...

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Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393204/
https://www.ncbi.nlm.nih.gov/pubmed/22807772
http://dx.doi.org/10.1107/S1600536812026943
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author Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the title complex, [Ni(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 23.67 (8)°, while the pyridine and benzene rings are oriented at an angle of 89.04 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an O—H⋯O hydrogen bond. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π contacts between benzene rings [centroid–centroid distance = 3.8414 (7) Å] may further stabilize the structure. A weak C—H⋯π inter­action also occurs.
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spelling pubmed-33932042012-07-17 Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II) Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 23.67 (8)°, while the pyridine and benzene rings are oriented at an angle of 89.04 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an O—H⋯O hydrogen bond. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π contacts between benzene rings [centroid–centroid distance = 3.8414 (7) Å] may further stabilize the structure. A weak C—H⋯π inter­action also occurs. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393204/ /pubmed/22807772 http://dx.doi.org/10.1107/S1600536812026943 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title_full Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title_fullStr Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title_full_unstemmed Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title_short Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))nickel(II)
title_sort diaqua­bis­(4-formyl­benzoato-κo (1))bis­(nicotinamide-κn (1))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393204/
https://www.ncbi.nlm.nih.gov/pubmed/22807772
http://dx.doi.org/10.1107/S1600536812026943
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