Cargando…

Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)

In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta­coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl­oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipy...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yu-Hong, Zhu, Xue-Hua, Song, Rui-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393207/
https://www.ncbi.nlm.nih.gov/pubmed/22807775
http://dx.doi.org/10.1107/S1600536812026591
_version_ 1782237695795265536
author Wang, Yu-Hong
Zhu, Xue-Hua
Song, Rui-Feng
author_facet Wang, Yu-Hong
Zhu, Xue-Hua
Song, Rui-Feng
author_sort Wang, Yu-Hong
collection PubMed
description In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta­coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl­oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl inter­action, leading to a distorted octa­hedral coordination geometry around the Hg(II) ion.
format Online
Article
Text
id pubmed-3393207
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932072012-07-17 Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II) Wang, Yu-Hong Zhu, Xue-Hua Song, Rui-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta­coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl­oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl inter­action, leading to a distorted octa­hedral coordination geometry around the Hg(II) ion. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393207/ /pubmed/22807775 http://dx.doi.org/10.1107/S1600536812026591 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yu-Hong
Zhu, Xue-Hua
Song, Rui-Feng
Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title_full Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title_fullStr Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title_full_unstemmed Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title_short Dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) N,O)acetate-κO]mercury(II)
title_sort dichlorido[methyl 2-(quinolin-8-yl­oxy-κ(2) n,o)acetate-κo]mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393207/
https://www.ncbi.nlm.nih.gov/pubmed/22807775
http://dx.doi.org/10.1107/S1600536812026591
work_keys_str_mv AT wangyuhong dichloridomethyl2quinolin8yloxyk2noacetatekomercuryii
AT zhuxuehua dichloridomethyl2quinolin8yloxyk2noacetatekomercuryii
AT songruifeng dichloridomethyl2quinolin8yloxyk2noacetatekomercuryii