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Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2) N,O)acetate-κO]mercury(II)
In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipy...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393207/ https://www.ncbi.nlm.nih.gov/pubmed/22807775 http://dx.doi.org/10.1107/S1600536812026591 |
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author | Wang, Yu-Hong Zhu, Xue-Hua Song, Rui-Feng |
author_facet | Wang, Yu-Hong Zhu, Xue-Hua Song, Rui-Feng |
author_sort | Wang, Yu-Hong |
collection | PubMed |
description | In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl interaction, leading to a distorted octahedral coordination geometry around the Hg(II) ion. |
format | Online Article Text |
id | pubmed-3393207 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932072012-07-17 Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2) N,O)acetate-κO]mercury(II) Wang, Yu-Hong Zhu, Xue-Hua Song, Rui-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl interaction, leading to a distorted octahedral coordination geometry around the Hg(II) ion. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393207/ /pubmed/22807775 http://dx.doi.org/10.1107/S1600536812026591 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yu-Hong Zhu, Xue-Hua Song, Rui-Feng Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2) N,O)acetate-κO]mercury(II) |
title | Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
N,O)acetate-κO]mercury(II) |
title_full | Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
N,O)acetate-κO]mercury(II) |
title_fullStr | Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
N,O)acetate-κO]mercury(II) |
title_full_unstemmed | Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
N,O)acetate-κO]mercury(II) |
title_short | Dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
N,O)acetate-κO]mercury(II) |
title_sort | dichlorido[methyl 2-(quinolin-8-yloxy-κ(2)
n,o)acetate-κo]mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393207/ https://www.ncbi.nlm.nih.gov/pubmed/22807775 http://dx.doi.org/10.1107/S1600536812026591 |
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