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(Bipyridine-κ(2) N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]zinc(II)
The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry....
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393212/ https://www.ncbi.nlm.nih.gov/pubmed/22807780 http://dx.doi.org/10.1107/S1600536812027626 |
| _version_ | 1782237696947650560 |
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| author | Mohamad, Fatin Allia Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Mohamad, Fatin Allia Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Mohamad, Fatin Allia |
| collection | PubMed |
| description | The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O—H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C—H⋯O, C—H⋯S and C—H⋯Cl interactions. |
| format | Online Article Text |
| id | pubmed-3393212 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33932122012-07-17 (Bipyridine-κ(2) N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]zinc(II) Mohamad, Fatin Allia Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O—H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C—H⋯O, C—H⋯S and C—H⋯Cl interactions. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393212/ /pubmed/22807780 http://dx.doi.org/10.1107/S1600536812027626 Text en © Mohamad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mohamad, Fatin Allia Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (Bipyridine-κ(2) N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]zinc(II) |
| title | (Bipyridine-κ(2)
N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]zinc(II) |
| title_full | (Bipyridine-κ(2)
N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]zinc(II) |
| title_fullStr | (Bipyridine-κ(2)
N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]zinc(II) |
| title_full_unstemmed | (Bipyridine-κ(2)
N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]zinc(II) |
| title_short | (Bipyridine-κ(2)
N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]zinc(II) |
| title_sort | (bipyridine-κ(2)
n,n′)chlorido[n-(2-hydroxyethyl)-n-isopropyldithiocarbamato-κ(2)
s,s′]zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393212/ https://www.ncbi.nlm.nih.gov/pubmed/22807780 http://dx.doi.org/10.1107/S1600536812027626 |
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