Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate

The title structure, [Ni(C(14)H(8)N(2)O(4))(H(2)O)(4)]·4H(2)O, contains a mononuclear Ni(II) complex formed by a chelating bidentate Schiff base and by four Ni-bonded water mol­ecules. The Ni(II) atom is in a distorted octa­hedral coordination by two N atoms in a cis disposition [Ni—N = 2.0753 (16)...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Huan-Huan, Duan, Guang-He, Wang, Lin, Xie, Ya-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393215/
https://www.ncbi.nlm.nih.gov/pubmed/22807783
http://dx.doi.org/10.1107/S1600536812027122
_version_ 1782237697646002176
author Wang, Huan-Huan
Duan, Guang-He
Wang, Lin
Xie, Ya-Bo
author_facet Wang, Huan-Huan
Duan, Guang-He
Wang, Lin
Xie, Ya-Bo
author_sort Wang, Huan-Huan
collection PubMed
description The title structure, [Ni(C(14)H(8)N(2)O(4))(H(2)O)(4)]·4H(2)O, contains a mononuclear Ni(II) complex formed by a chelating bidentate Schiff base and by four Ni-bonded water mol­ecules. The Ni(II) atom is in a distorted octa­hedral coordination by two N atoms in a cis disposition [Ni—N = 2.0753 (16) and 2.1048 (16) Å] and by four water O atoms [Ni—O = 2.0500 (15)–2.0822 (15) Å]. The crystal structure is completed by four further non-coordinating water mol­ecules and all constituents are linked in a three-dimensional manner by an extensive system of 16 O—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3393215
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932152012-07-17 Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate Wang, Huan-Huan Duan, Guang-He Wang, Lin Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, [Ni(C(14)H(8)N(2)O(4))(H(2)O)(4)]·4H(2)O, contains a mononuclear Ni(II) complex formed by a chelating bidentate Schiff base and by four Ni-bonded water mol­ecules. The Ni(II) atom is in a distorted octa­hedral coordination by two N atoms in a cis disposition [Ni—N = 2.0753 (16) and 2.1048 (16) Å] and by four water O atoms [Ni—O = 2.0500 (15)–2.0822 (15) Å]. The crystal structure is completed by four further non-coordinating water mol­ecules and all constituents are linked in a three-dimensional manner by an extensive system of 16 O—H⋯O hydrogen bonds. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393215/ /pubmed/22807783 http://dx.doi.org/10.1107/S1600536812027122 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Huan-Huan
Duan, Guang-He
Wang, Lin
Xie, Ya-Bo
Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title_full Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title_fullStr Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title_full_unstemmed Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title_short Tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) N,N′}nickel(II) tetra­hydrate
title_sort tetra­aqua­{5-[(pyridin-2-yl­methyl­idene)amino]benzene-1,3-dicarboxyl­ato-κ(2) n,n′}nickel(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393215/
https://www.ncbi.nlm.nih.gov/pubmed/22807783
http://dx.doi.org/10.1107/S1600536812027122
work_keys_str_mv AT wanghuanhuan tetraaqua5pyridin2ylmethylideneaminobenzene13dicarboxylatok2nnnickeliitetrahydrate
AT duanguanghe tetraaqua5pyridin2ylmethylideneaminobenzene13dicarboxylatok2nnnickeliitetrahydrate
AT wanglin tetraaqua5pyridin2ylmethylideneaminobenzene13dicarboxylatok2nnnickeliitetrahydrate
AT xieyabo tetraaqua5pyridin2ylmethylideneaminobenzene13dicarboxylatok2nnnickeliitetrahydrate

Ejemplares similares