Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate

Reaction of cobalt(II) nitrate with potassium seleno­cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio­cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno­cyanate lig...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393216/
https://www.ncbi.nlm.nih.gov/pubmed/22807784
http://dx.doi.org/10.1107/S1600536812027742
Descripción
Sumario:Reaction of cobalt(II) nitrate with potassium seleno­cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio­cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno­cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.

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