Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate

Reaction of cobalt(II) nitrate with potassium seleno­cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio­cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno­cyanate lig...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393216/
https://www.ncbi.nlm.nih.gov/pubmed/22807784
http://dx.doi.org/10.1107/S1600536812027742
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author Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description Reaction of cobalt(II) nitrate with potassium seleno­cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio­cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno­cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.
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spelling pubmed-33932162012-07-17 Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Reaction of cobalt(II) nitrate with potassium seleno­cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio­cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno­cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393216/ /pubmed/22807784 http://dx.doi.org/10.1107/S1600536812027742 Text en © Wöhlert et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title_full Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title_fullStr Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title_full_unstemmed Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title_short Tetra­kis(pyridazine-κN)bis­(seleno­cyanato-κN)cobalt(II) pyridazine disolvate
title_sort tetra­kis(pyridazine-κn)bis­(seleno­cyanato-κn)cobalt(ii) pyridazine disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393216/
https://www.ncbi.nlm.nih.gov/pubmed/22807784
http://dx.doi.org/10.1107/S1600536812027742
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