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Redetermination of (acetonitrile-κN)dicarbonyl(η(5)-cyclopentadienyl)iron(II) tetrafluoridoborate
The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is co...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393217/ https://www.ncbi.nlm.nih.gov/pubmed/22807785 http://dx.doi.org/10.1107/S1600536812027857 |
Sumario: | The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is coordinated by a cyclopentadienyl ring, two carbonyl ligands and an acetonitrile molecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF(4) (−) anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site. |
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