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Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate

The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is co...

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Detalles Bibliográficos
Autores principales: Kückmann, Theresa, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393217/
https://www.ncbi.nlm.nih.gov/pubmed/22807785
http://dx.doi.org/10.1107/S1600536812027857
Descripción
Sumario:The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is coordinated by a cyclo­penta­dienyl ring, two carbonyl ligands and an acetonitrile mol­ecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF(4) (−) anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site.