Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate

The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is co...

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Detalles Bibliográficos
Autores principales: Kückmann, Theresa, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393217/
https://www.ncbi.nlm.nih.gov/pubmed/22807785
http://dx.doi.org/10.1107/S1600536812027857
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author Kückmann, Theresa
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Kückmann, Theresa
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Kückmann, Theresa
collection PubMed
description The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is coordinated by a cyclo­penta­dienyl ring, two carbonyl ligands and an acetonitrile mol­ecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF(4) (−) anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site.
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spelling pubmed-33932172012-07-17 Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate Kückmann, Theresa Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The Fe(II) atom in the complex cation is coordinated by a cyclo­penta­dienyl ring, two carbonyl ligands and an acetonitrile mol­ecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF(4) (−) anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393217/ /pubmed/22807785 http://dx.doi.org/10.1107/S1600536812027857 Text en © Kückmann et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kückmann, Theresa
Lerner, Hans-Wolfram
Bolte, Michael
Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_full Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_fullStr Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_full_unstemmed Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_short Redetermination of (acetonitrile-κN)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II) tetra­fluoridoborate
title_sort redetermination of (acetonitrile-κn)dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393217/
https://www.ncbi.nlm.nih.gov/pubmed/22807785
http://dx.doi.org/10.1107/S1600536812027857
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