Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)

The title complex mol­ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(−) anions and four 1-[4-(1H-imidazol-1-yl)phen­yl]ethan­one ligands in a distorted octa­hedral geometry. In th...

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Detalles Bibliográficos
Autores principales: Zhao, Juan, Liu, Bao-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393218/
https://www.ncbi.nlm.nih.gov/pubmed/22807786
http://dx.doi.org/10.1107/S1600536812027092
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author Zhao, Juan
Liu, Bao-Cheng
author_facet Zhao, Juan
Liu, Bao-Cheng
author_sort Zhao, Juan
collection PubMed
description The title complex mol­ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(−) anions and four 1-[4-(1H-imidazol-1-yl)phen­yl]ethan­one ligands in a distorted octa­hedral geometry. In the crystal, C—H⋯S hydrogen bonds link the complex mol­ecules into chains parallel to the b axis. The chains are further connected by C—H⋯O hydrogen bonds, forming layers parallel to the bc plane.
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spelling pubmed-33932182012-07-17 Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II) Zhao, Juan Liu, Bao-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex mol­ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(−) anions and four 1-[4-(1H-imidazol-1-yl)phen­yl]ethan­one ligands in a distorted octa­hedral geometry. In the crystal, C—H⋯S hydrogen bonds link the complex mol­ecules into chains parallel to the b axis. The chains are further connected by C—H⋯O hydrogen bonds, forming layers parallel to the bc plane. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393218/ /pubmed/22807786 http://dx.doi.org/10.1107/S1600536812027092 Text en © Zhao and Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Juan
Liu, Bao-Cheng
Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title_full Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title_fullStr Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title_full_unstemmed Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title_short Tetra­kis{1-[4-(1H-imidazol-1-yl-κN (3))phen­yl]ethanone}bis­(isothio­cyanato-κN)nickel(II)
title_sort tetra­kis{1-[4-(1h-imidazol-1-yl-κn (3))phen­yl]ethanone}bis­(isothio­cyanato-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393218/
https://www.ncbi.nlm.nih.gov/pubmed/22807786
http://dx.doi.org/10.1107/S1600536812027092
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AT liubaocheng tetrakis141himidazol1ylkn3phenylethanonebisisothiocyanatoknnickelii

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