Cargando…
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water molecules in a distorted square-antiprismatic coodination environment. Adjacent La(III) atoms are...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393223/ https://www.ncbi.nlm.nih.gov/pubmed/22807791 http://dx.doi.org/10.1107/S1600536812027778 |
Sumario: | In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water molecules in a distorted square-antiprismatic coodination environment. Adjacent La(III) atoms are bridged by two carboxylate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intrachain O—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.908 (2) Å] are also observed. |
---|