Cargando…
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water molecules in a distorted square-antiprismatic coodination environment. Adjacent La(III) atoms are...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393223/ https://www.ncbi.nlm.nih.gov/pubmed/22807791 http://dx.doi.org/10.1107/S1600536812027778 |
_version_ | 1782237699530293248 |
---|---|
author | Zhao, Jin-He |
author_facet | Zhao, Jin-He |
author_sort | Zhao, Jin-He |
collection | PubMed |
description | In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water molecules in a distorted square-antiprismatic coodination environment. Adjacent La(III) atoms are bridged by two carboxylate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intrachain O—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.908 (2) Å] are also observed. |
format | Online Article Text |
id | pubmed-3393223 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932232012-07-17 catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride] Zhao, Jin-He Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water molecules in a distorted square-antiprismatic coodination environment. Adjacent La(III) atoms are bridged by two carboxylate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intrachain O—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.908 (2) Å] are also observed. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3393223/ /pubmed/22807791 http://dx.doi.org/10.1107/S1600536812027778 Text en © Jin-He Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Jin-He catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride] |
title |
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4)
O:O′] chloride] |
title_full |
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4)
O:O′] chloride] |
title_fullStr |
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4)
O:O′] chloride] |
title_full_unstemmed |
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4)
O:O′] chloride] |
title_short |
catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ(4)
O:O′] chloride] |
title_sort | catena-poly[[[tetraaqualanthanum(iii)]-di-μ-isonicotinato-κ(4)
o:o′] chloride] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393223/ https://www.ncbi.nlm.nih.gov/pubmed/22807791 http://dx.doi.org/10.1107/S1600536812027778 |
work_keys_str_mv | AT zhaojinhe catenapolytetraaqualanthanumiiidimisonicotinatok4oochloride |