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catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]

In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water mol­ecules in a distorted square-anti­prismatic coodination environment. Adjacent La(III) atoms are...

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Detalles Bibliográficos
Autor principal: Zhao, Jin-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393223/
https://www.ncbi.nlm.nih.gov/pubmed/22807791
http://dx.doi.org/10.1107/S1600536812027778
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author Zhao, Jin-He
author_facet Zhao, Jin-He
author_sort Zhao, Jin-He
collection PubMed
description In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water mol­ecules in a distorted square-anti­prismatic coodination environment. Adjacent La(III) atoms are bridged by two carboxyl­ate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intra­chain O—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.908 (2) Å] are also observed.
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spelling pubmed-33932232012-07-17 catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride] Zhao, Jin-He Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[La(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the La(III) atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water mol­ecules in a distorted square-anti­prismatic coodination environment. Adjacent La(III) atoms are bridged by two carboxyl­ate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intra­chain O—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.908 (2) Å] are also observed. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3393223/ /pubmed/22807791 http://dx.doi.org/10.1107/S1600536812027778 Text en © Jin-He Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jin-He
catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title_full catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title_fullStr catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title_full_unstemmed catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title_short catena-Poly[[[tetra­aqua­lanthanum(III)]-di-μ-isonicotinato-κ(4) O:O′] chloride]
title_sort catena-poly[[[tetra­aqua­lanthanum(iii)]-di-μ-isonicotinato-κ(4) o:o′] chloride]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393223/
https://www.ncbi.nlm.nih.gov/pubmed/22807791
http://dx.doi.org/10.1107/S1600536812027778
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