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Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]sodium trifluoromethanesulfonate
In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris(3,5-dimethylpyrazol-1-yl)methane ligands in a distorted octahedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393224/ https://www.ncbi.nlm.nih.gov/pubmed/22807792 http://dx.doi.org/10.1107/S1600536812028413 |
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author | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad |
author_facet | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad |
author_sort | Lyubartseva, Ganna |
collection | PubMed |
description | In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris(3,5-dimethylpyrazol-1-yl)methane ligands in a distorted octahedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N—Na—N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoromethanesulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)]. |
format | Online Article Text |
id | pubmed-3393224 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932242012-07-17 Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]sodium trifluoromethanesulfonate Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris(3,5-dimethylpyrazol-1-yl)methane ligands in a distorted octahedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N—Na—N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoromethanesulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393224/ /pubmed/22807792 http://dx.doi.org/10.1107/S1600536812028413 Text en © Lyubartseva et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))methyl]sodium trifluoromethanesulfonate |
title | Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))methyl]sodium trifluoromethanesulfonate |
title_full | Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))methyl]sodium trifluoromethanesulfonate |
title_fullStr | Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))methyl]sodium trifluoromethanesulfonate |
title_full_unstemmed | Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))methyl]sodium trifluoromethanesulfonate |
title_short | Bis[tris(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))methyl]sodium trifluoromethanesulfonate |
title_sort | bis[tris(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))methyl]sodium trifluoromethanesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393224/ https://www.ncbi.nlm.nih.gov/pubmed/22807792 http://dx.doi.org/10.1107/S1600536812028413 |
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