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Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate

In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris­(3,5-dimethyl­pyrazol-1-yl)methane ligands in a distorted octa­hedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from...

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Autores principales: Lyubartseva, Ganna, Parkin, Sean, Mallik, Uma Prasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393224/
https://www.ncbi.nlm.nih.gov/pubmed/22807792
http://dx.doi.org/10.1107/S1600536812028413
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author Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_facet Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_sort Lyubartseva, Ganna
collection PubMed
description In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris­(3,5-dimethyl­pyrazol-1-yl)methane ligands in a distorted octa­hedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N—Na—N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoro­methane­sulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)].
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spelling pubmed-33932242012-07-17 Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Na(C(16)H(22)N(6))(2)]CF(3)SO(3), the Na(+) cation is coordinated by six N atoms from two tridentate tris­(3,5-dimethyl­pyrazol-1-yl)methane ligands in a distorted octa­hedral geometry. The Na—N distances range from 2.427 (3) to 2.507 (3) Å, intra-ligand N—Na—N angles range from 74.71 (8) to 79.31 (9)°, and adjacent inter-ligand N—Na—N angles range between 100.42 (9) and 104.97 (9)°. The structure is twinned by inversion [occupancy factors = 0.50 (9)] and the trifluoro­methane­sulfonate anion is disordered, with two end-over-end orientations of unequal occupancy [0.781 (3) and 0.219 (3)]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393224/ /pubmed/22807792 http://dx.doi.org/10.1107/S1600536812028413 Text en © Lyubartseva et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title_full Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title_fullStr Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title_full_unstemmed Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title_short Bis[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))meth­yl]sodium trifluoro­methane­sulfonate
title_sort bis[tris­(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))meth­yl]sodium trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393224/
https://www.ncbi.nlm.nih.gov/pubmed/22807792
http://dx.doi.org/10.1107/S1600536812028413
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