Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium

In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis­phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion...

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Detalles Bibliográficos
Autores principales: Reza, M. S., Islam, M. A. A. A. A., Tarafder, M. T. H., Sheikh, M. C., Zangrando, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393227/
https://www.ncbi.nlm.nih.gov/pubmed/22807795
http://dx.doi.org/10.1107/S1600536812028127
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author Reza, M. S.
Islam, M. A. A. A. A.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
author_facet Reza, M. S.
Islam, M. A. A. A. A.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
author_sort Reza, M. S.
collection PubMed
description In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis­phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol­ate S atom. The dihedral angle between the two chelating ligands is 84.01 (9)°. Weak inter­molecular C—H⋯S inter­actions lead to the formation of chains along the c axis.
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spelling pubmed-33932272012-07-17 Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium Reza, M. S. Islam, M. A. A. A. A. Tarafder, M. T. H. Sheikh, M. C. Zangrando, E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis­phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol­ate S atom. The dihedral angle between the two chelating ligands is 84.01 (9)°. Weak inter­molecular C—H⋯S inter­actions lead to the formation of chains along the c axis. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393227/ /pubmed/22807795 http://dx.doi.org/10.1107/S1600536812028127 Text en © Reza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reza, M. S.
Islam, M. A. A. A. A.
Tarafder, M. T. H.
Sheikh, M. C.
Zangrando, E.
Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title_full Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title_fullStr Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title_full_unstemmed Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title_short Bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) N (3),S]cadmium
title_sort bis[benzyl 3-(3-phenyl­prop-2-enyl­idene)dithio­carbazato-κ(2) n (3),s]cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393227/
https://www.ncbi.nlm.nih.gov/pubmed/22807795
http://dx.doi.org/10.1107/S1600536812028127
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