3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one

The title ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(16)H(16)NO(2))], crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecules A and B have similar conformations. The dihedral angles between the best planes of the benzene and substituted cyclo­penta­dienyl ri...

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Detalles Bibliográficos
Autores principales: Novaković, Sladjana B., Stevanović, Dragana, Divjaković, Vladimir, Bogdanović, Goran A., Vukićević, Rastko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393229/
https://www.ncbi.nlm.nih.gov/pubmed/22807797
http://dx.doi.org/10.1107/S1600536812028796
Descripción
Sumario:The title ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(16)H(16)NO(2))], crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecules A and B have similar conformations. The dihedral angles between the best planes of the benzene and substituted cyclo­penta­dienyl rings are 88.59 (9) and 84.39 (10)° in A and B, respectively. In the crystal, the independent mol­ecules form centrosymmetric dimers via corresponding N—H⋯O hydrogen bonds. The dimers further arrange via C—H⋯π and C—H⋯O inter­actions. There are no significant inter­actions between the A and B mol­ecules.

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