3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one

The title ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(16)H(16)NO(2))], crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecules A and B have similar conformations. The dihedral angles between the best planes of the benzene and substituted cyclo­penta­dienyl ri...

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Autores principales: Novaković, Sladjana B., Stevanović, Dragana, Divjaković, Vladimir, Bogdanović, Goran A., Vukićević, Rastko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393229/
https://www.ncbi.nlm.nih.gov/pubmed/22807797
http://dx.doi.org/10.1107/S1600536812028796
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author Novaković, Sladjana B.
Stevanović, Dragana
Divjaković, Vladimir
Bogdanović, Goran A.
Vukićević, Rastko D.
author_facet Novaković, Sladjana B.
Stevanović, Dragana
Divjaković, Vladimir
Bogdanović, Goran A.
Vukićević, Rastko D.
author_sort Novaković, Sladjana B.
collection PubMed
description The title ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(16)H(16)NO(2))], crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecules A and B have similar conformations. The dihedral angles between the best planes of the benzene and substituted cyclo­penta­dienyl rings are 88.59 (9) and 84.39 (10)° in A and B, respectively. In the crystal, the independent mol­ecules form centrosymmetric dimers via corresponding N—H⋯O hydrogen bonds. The dimers further arrange via C—H⋯π and C—H⋯O inter­actions. There are no significant inter­actions between the A and B mol­ecules.
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spelling pubmed-33932292012-07-17 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one Novaković, Sladjana B. Stevanović, Dragana Divjaković, Vladimir Bogdanović, Goran A. Vukićević, Rastko D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title ferrocene-containing Mannich base, [Fe(C(5)H(5))(C(16)H(16)NO(2))], crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecules A and B have similar conformations. The dihedral angles between the best planes of the benzene and substituted cyclo­penta­dienyl rings are 88.59 (9) and 84.39 (10)° in A and B, respectively. In the crystal, the independent mol­ecules form centrosymmetric dimers via corresponding N—H⋯O hydrogen bonds. The dimers further arrange via C—H⋯π and C—H⋯O inter­actions. There are no significant inter­actions between the A and B mol­ecules. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393229/ /pubmed/22807797 http://dx.doi.org/10.1107/S1600536812028796 Text en © Novaković et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Novaković, Sladjana B.
Stevanović, Dragana
Divjaković, Vladimir
Bogdanović, Goran A.
Vukićević, Rastko D.
3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title_full 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title_fullStr 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title_full_unstemmed 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title_short 3-(3-Acetyl­anilino)-1-ferrocenylpropan-1-one
title_sort 3-(3-acetyl­anilino)-1-ferrocenylpropan-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393229/
https://www.ncbi.nlm.nih.gov/pubmed/22807797
http://dx.doi.org/10.1107/S1600536812028796
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