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6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III)
In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distance = 3.5419 (19) Å] result in the formation of a sup...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393230/ https://www.ncbi.nlm.nih.gov/pubmed/22807798 http://dx.doi.org/10.1107/S160053681202853X |
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author | Zare Dehnavi, Marzieh Abedi, Anita |
author_facet | Zare Dehnavi, Marzieh Abedi, Anita |
author_sort | Zare Dehnavi, Marzieh |
collection | PubMed |
description | In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distance = 3.5419 (19) Å] result in the formation of a supramolecular structure. |
format | Online Article Text |
id | pubmed-3393230 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33932302012-07-17 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) Zare Dehnavi, Marzieh Abedi, Anita Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distance = 3.5419 (19) Å] result in the formation of a supramolecular structure. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393230/ /pubmed/22807798 http://dx.doi.org/10.1107/S160053681202853X Text en © Zare Dehnavi and Abedi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zare Dehnavi, Marzieh Abedi, Anita 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title | 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title_full | 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title_fullStr | 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title_full_unstemmed | 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title_short | 6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III) |
title_sort | 6,6′-dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393230/ https://www.ncbi.nlm.nih.gov/pubmed/22807798 http://dx.doi.org/10.1107/S160053681202853X |
work_keys_str_mv | AT zaredehnavimarzieh 66dimethyl22bipyridin1iumtetrachloridoaurateiii AT abedianita 66dimethyl22bipyridin1iumtetrachloridoaurateiii |