(Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)

In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O′-donor ligand, derived from the condensation of salicyl­aldehyde and l-isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. T...

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Detalles Bibliográficos
Autores principales: Wang, Chengyuan, Guo, Zhenghua, Dong, Jianfang, Li, Lianzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393231/
https://www.ncbi.nlm.nih.gov/pubmed/22807799
http://dx.doi.org/10.1107/S1600536812028231
Descripción
Sumario:In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O′-donor ligand, derived from the condensation of salicyl­aldehyde and l-isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. The asymmetric unit contains two complex mol­ecules. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds connect the mol­ecules into a one-dimensional chain along [100].

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