(Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)

In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O′-donor ligand, derived from the condensation of salicyl­aldehyde and l-isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Chengyuan, Guo, Zhenghua, Dong, Jianfang, Li, Lianzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393231/
https://www.ncbi.nlm.nih.gov/pubmed/22807799
http://dx.doi.org/10.1107/S1600536812028231
_version_ 1782237701376835584
author Wang, Chengyuan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
author_facet Wang, Chengyuan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
author_sort Wang, Chengyuan
collection PubMed
description In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O′-donor ligand, derived from the condensation of salicyl­aldehyde and l-isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. The asymmetric unit contains two complex mol­ecules. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds connect the mol­ecules into a one-dimensional chain along [100].
format Online
Article
Text
id pubmed-3393231
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33932312012-07-17 (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V) Wang, Chengyuan Guo, Zhenghua Dong, Jianfang Li, Lianzhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O′-donor ligand, derived from the condensation of salicyl­aldehyde and l-isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. The asymmetric unit contains two complex mol­ecules. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds connect the mol­ecules into a one-dimensional chain along [100]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393231/ /pubmed/22807799 http://dx.doi.org/10.1107/S1600536812028231 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chengyuan
Guo, Zhenghua
Dong, Jianfang
Li, Lianzhi
(Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title_full (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title_fullStr (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title_full_unstemmed (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title_short (Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)isoleucinato-κ(3) O,N,O′]vanadium(V)
title_sort (methanol-κo)(methano­lato-κo)oxido[n-(2-oxidobenzyl­idene)isoleucinato-κ(3) o,n,o′]vanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393231/
https://www.ncbi.nlm.nih.gov/pubmed/22807799
http://dx.doi.org/10.1107/S1600536812028231
work_keys_str_mv AT wangchengyuan methanolkomethanolatokooxidon2oxidobenzylideneisoleucinatok3onovanadiumv
AT guozhenghua methanolkomethanolatokooxidon2oxidobenzylideneisoleucinatok3onovanadiumv
AT dongjianfang methanolkomethanolatokooxidon2oxidobenzylideneisoleucinatok3onovanadiumv
AT lilianzhi methanolkomethanolatokooxidon2oxidobenzylideneisoleucinatok3onovanadiumv

Ejemplares similares